49 1001 Howell, S University of Hawaii Manoa Non-refractory aerosol composition from the Aerodyne AMS on the P-3B ARCTAS 1 1 2008 04 01 2010 12 31 0 Start_UTC, seconds, seconds from 0000 UTC 6 1 1 1 1 1 1 -9999 -9999 -9999 -9999 -9999 -9999 Stop_UTC, seconds, seconds from 0000 UTC Mid_UTC, seconds, seconds from 0000 UTC NO3, micrograms per standard meter cubed, Aerosol nitrate plus organic nitrate fragmants SO4, micrograms per standard meter cubed, Aerosol sulfate NH4, micrograms per standard meter cubed, Aerosol ammonium Org, micrograms per standard meter cubed, Aerosol non-refractory organic material 0 29 PI_CONTACT_INFO: email: sghowell@hawaii.edu; phone: 808-956-5185; address: Univ. Hawaii Dep't Ocean, 1000 Pope Rd, Honolulu, HI 96822 PLATFORM: NASA P-3B, using a solid diffuser inlet on the port side outside the front cabin LOCATION: Contained in aircraft data files. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Aerodyne aerosol mass spectrometer operating in V-mode, with heater near 600 C. This is bulk composition only (no size distributions). DATA_INFO: Units are micrograms per standard cubic meter (101325 Pa, 273 K). Particle sizes 50 to 500 nm vacuum aerodynamic diameter. UNCERTAINTY: 40% for accuracy, precision is much better, around 10% (2 sigma). To that add the detection limits 0.05, 0.05, 0.10, and 0.15. Values below detection limit are retained so averages work. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: ARCTAS Spring deployment, 31 March to 19 April 2008, http://www-air.larc.nasa.gov/missions/arctas/arctas.html STIPULATIONS_ON_USE: Ask investigator before publication for any further caveats. OTHER_COMMENTS: N/A REVISION: R1 R1: Transmission efficiency adjusted so per-flight median agrees with estimated volatile mass from OPC. Fragmentation table updated so masses during filter are near 0. Now averaged over 60 second periods to match 60s merge times. Higher time resolutions are available by request. Absolute amount has changed considerably from R0 but species ratios are nearly unchanged. R0: Not all calibration corrections are complete: Ionization efficiency is close, but transmission efficiency needs more work. Used a collection effeciency (CE) of max(0.5,(2-R)/2) where R is the mole ratio of NH4 to SO4. CE was smoothed with a 5 point box filter (about 1 minute). As there was no independent aerosol chemistry measurement, the CE will continue to have significant uncertainty, so it may be best to look at chemical ratios rather than absolute amount. Exact sampling times are not known exactly; recorded times are the end of sampling periods, but the mass spec open mode is 1 of 3 modes being used and the time of each mode is not recorded, so actual sample times may be a few seconds earlier than indicated. No allowances made for sampling delay due to inlet tubing length. Interference between air and NH4 peaks make quantifying the latter quite noisy; this will be improved in a later submission. There is a negative artifact in the organic signal at startup that decays over an hour or so; this will also be improved later. Start_UTC Stop_UTC Mid_UTC NO3 SO4 NH4 Org 63030 63090 63060 -9999 -9999 -9999 -9999 63090 63150 63120 -9999 -9999 -9999 -9999 63150 63210 63180 -9999 -9999 -9999 -9999 63210 63270 63240 -9999 -9999 -9999 -9999 63270 63330 63300 -9999 -9999 -9999 -9999 63330 63390 63360 -9999 -9999 -9999 -9999 63390 63450 63420 -9999 -9999 -9999 -9999 63450 63510 63480 -9999 -9999 -9999 -9999 63510 63570 63540 -9999 -9999 -9999 -9999 63570 63630 63600 -9999 -9999 -9999 -9999 63630 63690 63660 -9999 -9999 -9999 -9999 63690 63750 63720 -9999 -9999 -9999 -9999 63750 63810 63780 -9999 -9999 -9999 -9999 63810 63870 63840 -9999 -9999 -9999 -9999 63870 63930 63900 -9999 -9999 -9999 -9999 63930 63990 63960 -9999 -9999 -9999 -9999 63990 64050 64020 -9999 -9999 -9999 -9999 64050 64110 64080 -9999 -9999 -9999 -9999 64110 64170 64140 -9999 -9999 -9999 -9999 64170 64230 64200 -9999 -9999 -9999 -9999 64230 64290 64260 -9999 -9999 -9999 -9999 64290 64350 64320 -9999 -9999 -9999 -9999 64350 64410 64380 -9999 -9999 -9999 -9999 64410 64470 64440 -9999 -9999 -9999 -9999 64470 64530 64500 -9999 -9999 -9999 -9999 64530 64590 64560 0.14 5.54 0.51 2.51 64590 64650 64620 0.14 5.85 0.62 2.39 64650 64710 64680 0.11 5.84 0.54 2.32 64710 64770 64740 0.11 5.51 0.50 2.45 64770 64830 64800 -9999 -9999 -9999 -9999 64830 64890 64860 -9999 -9999 -9999 -9999 64890 64950 64920 -9999 -9999 -9999 -9999 64950 65010 64980 -9999 -9999 -9999 -9999 65010 65070 65040 -9999 -9999 -9999 -9999 65070 65130 65100 -9999 -9999 -9999 -9999 65130 65190 65160 -9999 -9999 -9999 -9999 65190 65250 65220 -9999 -9999 -9999 -9999 65250 65310 65280 -9999 -9999 -9999 -9999 65310 65370 65340 -9999 -9999 -9999 -9999 65370 65430 65400 -9999 -9999 -9999 -9999 65430 65490 65460 0.02 0.65 -0.08 0.46 65490 65550 65520 0.02 0.54 -0.06 0.41 65550 65610 65580 0.07 1.13 0.04 0.58 65610 65670 65640 0.06 0.94 0.11 0.73 65670 65730 65700 0.05 0.85 0.07 0.38 65730 65790 65760 0.05 0.73 0.12 0.67 65790 65850 65820 0.07 1.02 0.11 0.62 65850 65910 65880 0.07 1.04 -0.04 0.70 65910 65970 65940 0.03 0.62 -0.03 0.50 65970 66030 66000 0.01 0.47 -0.01 0.48 66030 66090 66060 0.02 0.54 0.06 0.45 66090 66150 66120 0.04 0.62 0.03 0.67 66150 66210 66180 0.03 0.66 0.00 0.57 66210 66270 66240 0.05 0.80 0.05 0.62 66270 66330 66300 0.06 1.37 0.04 0.51 66330 66390 66360 0.07 2.12 0.24 0.93 66390 66450 66420 0.03 1.67 0.15 0.75 66450 66510 66480 0.02 1.13 0.12 0.55 66510 66570 66540 0.05 0.45 0.02 0.37 66570 66630 66600 0.02 0.35 -0.08 0.35 66630 66690 66660 -9999 -9999 -9999 -9999 66690 66750 66720 -9999 -9999 -9999 -9999 66750 66810 66780 -9999 -9999 -9999 -9999 66810 66870 66840 0.07 3.16 0.23 1.28 66870 66930 66900 0.06 2.41 0.18 1.16 66930 66990 66960 0.08 2.85 0.19 1.30 66990 67050 67020 0.08 2.98 0.30 1.36 67050 67110 67080 0.04 0.90 0.05 0.43 67110 67170 67140 0.01 0.29 -0.00 0.26 67170 67230 67200 0.05 2.08 0.22 1.10 67230 67290 67260 0.04 2.20 0.09 0.95 67290 67350 67320 0.05 1.60 0.11 0.79 67350 67410 67380 0.03 0.94 0.06 0.56 67410 67470 67440 0.03 0.44 0.02 0.25 67470 67530 67500 0.03 0.50 -0.01 0.32 67530 67590 67560 0.02 0.28 0.03 0.24 67590 67650 67620 0.03 0.27 -0.04 0.43 67650 67710 67680 0.01 0.29 -0.06 0.30 67710 67770 67740 0.03 0.39 -0.04 0.20 67770 67830 67800 -9999 -9999 -9999 -9999 67830 67890 67860 -9999 -9999 -9999 -9999 67890 67950 67920 -9999 -9999 -9999 -9999 67950 68010 67980 0.12 5.78 0.62 2.18 68010 68070 68040 0.09 3.08 0.24 1.38 68070 68130 68100 0.04 0.59 0.18 0.45 68130 68190 68160 0.04 0.37 0.05 0.29 68190 68250 68220 0.05 0.39 0.05 0.59 68250 68310 68280 -9999 -9999 -9999 -9999 68310 68370 68340 -9999 -9999 -9999 -9999 68370 68430 68400 -9999 -9999 -9999 -9999 68430 68490 68460 -9999 -9999 -9999 -9999 68490 68550 68520 -9999 -9999 -9999 -9999 68550 68610 68580 -9999 -9999 -9999 -9999 68610 68670 68640 -9999 -9999 -9999 -9999 68670 68730 68700 -9999 -9999 -9999 -9999 68730 68790 68760 -0.04 0.52 0.08 0.11 68790 68850 68820 0.00 0.58 -0.01 0.24 68850 68910 68880 0.04 0.47 0.11 0.32 68910 68970 68940 0.00 0.35 -0.03 0.36 68970 69030 69000 0.02 0.28 -0.02 0.10 69030 69090 69060 0.00 0.24 -0.06 0.20 69090 69150 69120 0.01 0.24 0.00 0.24 69150 69210 69180 0.02 0.21 -0.03 0.18 69210 69270 69240 0.02 0.22 0.02 0.13 69270 69330 69300 -0.01 0.16 -0.08 0.12 69330 69390 69360 0.00 0.18 0.04 0.24 69390 69450 69420 0.01 0.24 -0.04 0.19 69450 69510 69480 0.02 0.21 -0.04 0.27 69510 69570 69540 0.02 0.16 -0.01 0.12 69570 69630 69600 0.01 0.20 -0.03 0.11 69630 69690 69660 0.05 0.24 0.03 0.23 69690 69750 69720 0.00 0.22 0.01 0.18 69750 69810 69780 0.00 0.17 -0.00 0.29 69810 69870 69840 -0.01 0.19 0.02 0.18 69870 69930 69900 0.01 0.17 -0.11 0.15 69930 69990 69960 0.02 0.28 0.04 0.17 69990 70050 70020 0.03 0.31 -0.02 0.17 70050 70110 70080 0.02 0.33 -0.00 0.18 70110 70170 70140 0.02 0.31 -0.04 0.22 70170 70230 70200 0.02 0.40 -0.02 0.15 70230 70290 70260 0.01 0.46 0.05 0.25 70290 70350 70320 0.03 0.40 -0.02 0.33 70350 70410 70380 0.02 0.45 0.06 0.13 70410 70470 70440 0.01 0.47 0.02 0.16 70470 70530 70500 0.00 0.47 -0.07 0.42 70530 70590 70560 0.05 0.72 0.13 0.40 70590 70650 70620 0.05 0.78 0.20 0.53 70650 70710 70680 0.04 0.76 0.14 0.13 70710 70770 70740 0.02 0.74 0.11 0.54 70770 70830 70800 0.04 0.63 0.11 0.38 70830 70890 70860 0.03 0.60 0.11 0.26 70890 70950 70920 0.05 0.52 0.12 0.40 70950 71010 70980 -0.01 0.51 0.03 0.24 71010 71070 71040 0.02 0.54 0.13 0.23 71070 71130 71100 0.01 0.47 0.03 0.31 71130 71190 71160 0.02 0.37 0.04 0.29 71190 71250 71220 0.03 0.45 0.03 0.32 71250 71310 71280 0.02 0.44 0.07 0.35 71310 71370 71340 -0.01 0.38 0.08 0.22 71370 71430 71400 0.03 0.35 0.04 0.22 71430 71490 71460 0.01 0.37 0.02 0.14 71490 71550 71520 0.02 0.44 0.00 0.24 71550 71610 71580 0.01 0.50 0.02 0.16 71610 71670 71640 -0.00 0.51 -0.01 0.25 71670 71730 71700 0.00 0.76 0.12 0.15 71730 71790 71760 0.02 0.61 -0.01 0.20 71790 71850 71820 0.02 0.52 0.03 0.20 71850 71910 71880 0.03 0.27 0.01 0.14 71910 71970 71940 0.03 0.41 -0.01 0.21 71970 72030 72000 0.01 0.56 0.06 0.18 72030 72090 72060 0.02 0.49 0.01 0.21 72090 72150 72120 0.03 1.25 0.10 0.40 72150 72210 72180 0.02 0.62 0.10 0.40 72210 72270 72240 0.03 0.47 -0.01 0.61 72270 72330 72300 0.02 0.50 0.04 0.32 72330 72390 72360 0.04 0.63 0.02 0.45 72390 72450 72420 0.01 0.50 0.06 0.41 72450 72510 72480 0.01 0.58 0.11 0.51 72510 72570 72540 0.00 0.43 0.05 0.30 72570 72630 72600 0.01 0.85 0.02 0.33 72630 72690 72660 0.00 0.40 0.00 0.26 72690 72750 72720 0.01 0.29 -0.02 0.24 72750 72810 72780 0.01 0.31 0.04 0.25 72810 72870 72840 -0.01 0.33 0.05 0.27 72870 72930 72900 -9999 -9999 -9999 -9999 72930 72990 72960 -0.01 0.41 0.05 0.25 72990 73050 73020 0.00 0.31 -0.02 0.20 73050 73110 73080 0.02 0.30 0.05 0.27 73110 73170 73140 0.01 0.37 0.08 0.26 73170 73230 73200 0.01 0.36 -0.06 0.32 73230 73290 73260 0.02 0.32 0.03 0.31 73290 73350 73320 0.01 0.33 0.05 0.25 73350 73410 73380 0.01 0.32 -0.01 0.32 73410 73470 73440 -0.01 0.31 0.05 0.14 73470 73530 73500 -9999 -9999 -9999 -9999 73530 73590 73560 0.01 0.03 0.06 0.18 73590 73650 73620 0.01 0.05 -0.05 0.15 73650 73710 73680 -0.01 0.03 0.06 0.13 73710 73770 73740 -0.01 0.14 -0.00 0.14 73770 73830 73800 0.00 0.10 -0.03 -0.03 73830 73890 73860 0.00 0.02 -0.02 0.09 73890 73950 73920 -0.00 0.04 -0.03 0.23 73950 74010 73980 -0.00 0.21 0.03 0.05 74010 74070 74040 -0.00 0.12 -0.03 0.16 74070 74130 74100 -0.00 0.23 0.01 0.19 74130 74190 74160 -9999 -9999 -9999 -9999 74190 74250 74220 -9999 -9999 -9999 -9999 74250 74310 74280 -9999 -9999 -9999 -9999 74310 74370 74340 -0.01 0.05 0.00 0.05 74370 74430 74400 0.02 0.40 0.08 0.23 74430 74490 74460 0.01 0.50 0.05 0.44 74490 74550 74520 0.02 0.41 0.03 0.33 74550 74610 74580 0.05 0.60 0.14 0.66 74610 74670 74640 -9999 -9999 -9999 -9999 74670 74730 74700 -9999 -9999 -9999 -9999 74730 74790 74760 -0.00 1.02 0.09 0.21 74790 74850 74820 0.01 0.94 0.05 0.20 74850 74910 74880 0.02 0.30 -0.03 0.19 74910 74970 74940 0.00 0.33 -0.03 0.14 74970 75030 75000 0.00 0.22 -0.01 0.17 75030 75090 75060 0.00 0.19 -0.08 0.14 75090 75150 75120 0.02 0.37 0.00 0.12 75150 75210 75180 -0.01 0.39 0.06 0.20 75210 75270 75240 0.01 0.44 0.01 0.08 75270 75330 75300 -0.01 0.48 0.09 0.37 75330 75390 75360 0.01 0.54 -0.01 0.25 75390 75450 75420 0.00 0.46 0.02 0.20 75450 75510 75480 0.01 0.38 -0.06 0.15 75510 75570 75540 0.00 0.14 0.01 0.16 75570 75630 75600 0.01 0.47 0.03 0.08 75630 75690 75660 0.01 0.34 0.02 0.14 75690 75750 75720 0.00 0.31 0.01 0.10 75750 75810 75780 0.01 0.31 0.01 0.15 75810 75870 75840 0.00 0.38 0.07 0.11 75870 75930 75900 -0.01 0.45 0.06 0.05 75930 75990 75960 -0.00 0.78 -0.00 0.31 75990 76050 76020 0.02 0.67 0.04 0.22 76050 76110 76080 0.01 0.64 0.11 0.18 76110 76170 76140 0.02 0.55 0.07 0.21 76170 76230 76200 0.01 0.57 0.05 0.22 76230 76290 76260 0.04 0.73 0.14 0.31 76290 76350 76320 -9999 -9999 -9999 -9999 76350 76410 76380 -9999 -9999 -9999 -9999 76410 76470 76440 -9999 -9999 -9999 -9999 76470 76530 76500 -9999 -9999 -9999 -9999 76530 76590 76560 -9999 -9999 -9999 -9999 76590 76650 76620 -9999 -9999 -9999 -9999 76650 76710 76680 -9999 -9999 -9999 -9999 76710 76770 76740 0.02 0.75 0.09 0.20 76770 76830 76800 0.01 0.63 0.07 0.36 76830 76890 76860 0.01 0.70 0.06 0.17 76890 76950 76920 -0.00 0.71 0.14 0.30 76950 77010 76980 0.03 0.98 0.18 0.35 77010 77070 77040 0.02 0.96 0.11 0.38 77070 77130 77100 0.00 0.96 0.21 0.30 77130 77190 77160 0.03 1.02 0.19 0.44 77190 77250 77220 0.01 0.92 0.05 0.40 77250 77310 77280 0.03 0.74 0.11 0.24 77310 77370 77340 0.01 0.55 0.09 0.38 77370 77430 77400 -0.00 0.47 0.03 0.21 77430 77490 77460 -0.00 0.50 0.05 0.27 77490 77550 77520 0.01 0.51 0.09 0.20 77550 77610 77580 0.02 0.45 0.02 0.34 77610 77670 77640 0.01 0.48 0.01 0.24 77670 77730 77700 -0.00 0.44 0.07 0.28 77730 77790 77760 0.01 0.58 0.04 0.39 77790 77850 77820 0.03 0.63 0.15 0.25 77850 77910 77880 0.02 2.22 0.47 0.65 77910 77970 77940 0.03 2.25 0.41 0.71 77970 78030 78000 0.05 4.66 0.85 1.29 78030 78090 78060 0.06 5.05 0.87 1.47 78090 78150 78120 0.08 5.17 0.87 1.59 78150 78210 78180 0.05 4.79 0.82 1.36 78210 78270 78240 0.02 2.02 0.33 0.68 78270 78330 78300 0.01 0.29 -0.00 0.16 78330 78390 78360 0.02 0.17 0.00 0.21 78390 78450 78420 0.01 0.20 0.03 0.16 78450 78510 78480 0.01 0.18 -0.04 0.16 78510 78570 78540 0.01 0.21 0.03 0.22 78570 78630 78600 0.01 0.20 0.02 0.09 78630 78690 78660 0.01 0.22 -0.03 0.09 78690 78750 78720 0.00 0.21 -0.02 0.15 78750 78810 78780 -0.00 0.21 -0.01 0.14 78810 78870 78840 0.01 0.31 -0.03 0.11 78870 78930 78900 0.01 0.34 0.08 0.23 78930 78990 78960 0.01 0.26 -0.01 0.15 78990 79050 79020 -0.00 0.50 0.01 0.21 79050 79110 79080 0.00 0.75 0.13 0.21 79110 79170 79140 0.02 1.71 0.30 0.49 79170 79230 79200 0.04 1.50 0.25 0.48 79230 79290 79260 0.02 1.58 0.25 0.42 79290 79350 79320 0.01 1.33 0.17 0.48 79350 79410 79380 0.02 1.34 0.24 0.58 79410 79470 79440 0.01 1.47 0.22 0.59 79470 79530 79500 0.02 1.89 0.29 0.64 79530 79590 79560 0.02 1.84 0.28 0.54 79590 79650 79620 0.02 1.94 0.24 0.50 79650 79710 79680 0.02 1.83 0.25 0.39 79710 79770 79740 -0.00 1.79 0.27 0.48 79770 79830 79800 0.03 1.75 0.23 0.50 79830 79890 79860 0.02 1.72 0.25 0.52 79890 79950 79920 0.01 1.84 0.28 0.41 79950 80010 79980 0.01 1.74 0.20 0.43 80010 80070 80040 0.03 1.82 0.22 0.45 80070 80130 80100 -0.01 1.90 0.19 0.54 80130 80190 80160 -0.00 1.50 0.26 0.37 80190 80250 80220 0.01 1.18 0.14 0.35 80250 80310 80280 -0.01 0.84 0.15 0.20 80310 80370 80340 0.00 1.09 0.13 0.19 80370 80430 80400 0.02 1.59 0.16 0.24 80430 80490 80460 0.01 2.24 0.21 0.31 80490 80550 80520 0.02 2.90 0.29 0.57 80550 80610 80580 0.02 2.66 0.25 0.50 80610 80670 80640 0.00 2.04 0.24 0.44 80670 80730 80700 0.01 1.38 0.11 0.17 80730 80790 80760 0.01 1.55 0.13 0.27 80790 80850 80820 0.00 0.89 0.06 0.27 80850 80910 80880 -9999 -9999 -9999 -9999 80910 80970 80940 -9999 -9999 -9999 -9999 80970 81030 81000 0.00 0.42 0.01 0.16 81030 81090 81060 0.00 0.31 0.01 0.12 81090 81150 81120 -0.00 0.22 0.02 0.09 81150 81210 81180 0.00 0.20 0.01 0.10 81210 81270 81240 -0.00 0.10 -0.02 0.05 81270 81330 81300 0.00 0.04 -0.01 0.06 81330 81390 81360 0.00 0.08 -0.00 0.09 81390 81450 81420 0.01 0.13 -0.01 0.10 81450 81510 81480 -0.00 0.08 0.02 0.05 81510 81570 81540 0.00 0.04 -0.01 0.09 81570 81630 81600 -0.00 0.03 -0.03 0.07 81630 81690 81660 -0.00 0.03 -0.00 0.10 81690 81750 81720 -0.00 0.02 -0.01 0.12 81750 81810 81780 0.00 0.11 0.01 0.10 81810 81870 81840 0.00 0.17 -0.02 0.11 81870 81930 81900 0.00 0.19 0.00 0.11 81930 81990 81960 -0.00 0.21 -0.00 0.11 81990 82050 82020 0.00 0.28 0.01 0.11 82050 82110 82080 0.00 0.33 0.03 0.12 82110 82170 82140 0.00 0.48 0.03 0.13 82170 82230 82200 0.00 0.63 0.04 0.19 82230 82290 82260 0.00 0.68 0.04 0.19 82290 82350 82320 0.00 0.94 0.07 0.25 82350 82410 82380 0.00 0.49 0.05 0.16 82410 82470 82440 0.00 0.52 0.04 0.10 82470 82530 82500 0.01 0.65 0.04 0.17 82530 82590 82560 0.00 0.55 0.03 0.11 82590 82650 82620 -0.00 0.26 -0.01 0.08 82650 82710 82680 0.01 0.14 0.00 0.06 82710 82770 82740 -0.00 0.12 0.01 0.09 82770 82830 82800 0.00 0.25 -0.01 0.12 82830 82890 82860 -0.00 0.15 0.01 0.07 82890 82950 82920 0.00 0.15 -0.01 0.07 82950 83010 82980 0.00 0.06 0.00 0.07 83010 83070 83040 -0.01 0.02 -0.00 0.07 83070 83130 83100 0.01 0.03 -0.03 0.09 83130 83190 83160 -0.00 0.04 0.00 0.05 83190 83250 83220 -0.00 0.04 0.01 0.12 83250 83310 83280 0.00 0.03 0.00 0.09 83310 83370 83340 -0.00 0.02 -0.03 0.06 83370 83430 83400 0.01 0.03 -0.02 0.06 83430 83490 83460 -0.01 0.01 0.02 0.12 83490 83550 83520 -9999 -9999 -9999 -9999 83550 83610 83580 -9999 -9999 -9999 -9999 83610 83670 83640 -9999 -9999 -9999 -9999 83670 83730 83700 -9999 -9999 -9999 -9999 83730 83790 83760 -9999 -9999 -9999 -9999 83790 83850 83820 -9999 -9999 -9999 -9999 83850 83910 83880 -9999 -9999 -9999 -9999 83910 83970 83940 -9999 -9999 -9999 -9999 83970 84030 84000 -9999 -9999 -9999 -9999 84030 84090 84060 -9999 -9999 -9999 -9999 84090 84150 84120 -9999 -9999 -9999 -9999 84150 84210 84180 -9999 -9999 -9999 -9999 84210 84270 84240 -9999 -9999 -9999 -9999 84270 84330 84300 -9999 -9999 -9999 -9999